I recently had my air con sorted.
Took it to a friends garage, who gave me some useful info. He connected the recharging machine, which apparently is a pain because they don't have a low pressure connector on these systems. It makes it easier to get the old gas out, but isn't an issue, it just takes longer sucking it out of the high pressure connection. Once cleaned out, it tests the system by creating a vacuum in the AC system, and waiting ten minutes. If the system has a leak, the vacuum decreases, and by law, shouldn't be recharged as the refrigerant is harmful to the environment. Mine passed, so onto the next stage, which is pumping a tiny amount of oil into the system, then the refrigerant. It worked briefly, then stopped. My mate isn't too au fait with AC systems, so I took it to a specialist. He drained it again, and checked it, but still no cold air. He drained it again, and told me he suspected the pressure switch was faulty. I left it with him, and he replaced it, gassed it up, and voila! Nice and cold

The switch wasn't very expensive. I think he uses pattern parts, which are way cheaper than Renault originals. I forget how much the switch was, but he only charged me £100.
There are plenty available on Ebay:
http://www.ebay.co.uk/sch/i.html?_from=R40&_trksid=p2060353.m570.l1313.TR1.TRC0.A0.H0.Xmegane+ac+pressure+switch.TRS0&_nkw=megane+ac+pressure+switch&_sacat=0:
If you wanted to change it yourself, the system would need to be emptied, as removing it under pressure is not only illegal, but may well be dangerous?
Maybe have a word with a local AC specialist, and ask him how much to do the job if you remove all the belly pans etc, so he can get at it? I hate presuming about how easy a professionals job is, but it appears to be a simple job, especially with the belly pan/rain guards removed?
If the system isn't charged, it should be an easy job, it appears to be a simple pressure sensor with a connector on one end, and a thread on the other. Removing the electrical connector, and get a spanner on the other end should take seconds?
By the way, you could check if the system is charged, by gently depressing the valve in the high pressure connector on the metal pipe at the top left of the engine. Don't hold the valve down for too long, as all the gas would escape.
This would just be a quick way of testing it of course

If the system was empty, and you replaced the pressure sensor, next stop is kwikfit to get it re-gassed. If it still isn't working, then at least you don't pay for it, and know that it is something more serious like the compressor.
Edit to add:
It appears that a replacement compressor isn't that steep either. I suppose it depends on how confident/competent you are at having a go yourself?
https://www.ebay.co.uk/sch/i.html?_from= ... r&_sacat=0Further edit:
Condensers aren't that expensive either
https://www.ebay.co.uk/sch/i.html?_odkw= ... r&_sacat=0